This solution comes from: http://www.tek-tips.com/viewthread.cfm?qid=1225579&page=1
Windows XP with SP2. IBM T43, actually. The problem materialized after I did a driver update (ThinkVantage Software Installer) and rebooted the system. Running F-Secure Client Security 6.01.
Error 720: A connection to the remote computer could not be established. You might need to change the network settings for this connection. (See screenshot below.)
I had confirmed that PPTP was properly selected as VPN type (VPNing into ISA 2004 with latest service pack via RRAS).